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This routine uses code built in 10 and other earlier chapters. When it detects an authorized user (the LoggedInUserID variable), it creates a SqlDataReader object with that user s allowed security features, and stores those settings in the SecurityProfile array. Once it is loaded, any array element that is True represents an application feature that the administrator is authorized to use. I ll discuss the GroupActivity table a little later in this chapter. If a database error occurs during processing, the code resets everything to patron mode, making a recursive call to ReprocessSecuritySet to clear the SecurityProfile array. (Recursion occurs when a routine directly or indirectly calls itself.)

Values of the parameters are given in Table C1 of App C for a number of common organic and inorganic gases More accurate but more complex equations are found in the literature' As a result of Eq (318), the two ideal-gas heat capacities are related:

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The temperature dependence of C$IR follows from the temperature dependence of C ~ I R The effects of temperature on Cig or C: are determined by experiment, most often calculated by the methods of statistical mechanics from spectroscopic data and knowledge of molecular structure Where experimental data are not available, methods of estimation are employed, as described by Reid, Prausnitz, and Poling'

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'see F A Aly and L L Lee, Fluid Phase Equilibria, vol 6, pp 169-179, 1981, and its bibliography; see also T E Daubert, R P Danner, H M Sibul, and C C Stebbins, Physical and Thermodynamic Properties of Pure Chemicals: Data Compilation, Taylor & Francis, Bristol, PA, extant 1995 'R Reid, J M Prausnitz, and B E Poling, The Properties of Gases andLiquids, 4th ed, chap 6, McGraw-Hill, C New York, 1987

name, but it also removed some of the barriers that kept entry-level programmers from approaching the language. Pre-.NET features, such as Edit and Continue and the display of forms through the simple use of the form s name, once again found their way into the language and into the hearts of software engineers. Visual Basic still retained all the power it gained with .NET, but with true improvements in usability. It was like when they add a label to your toothpaste that says, New package, same great regular flavor! Except that Visual Basic s flavor was improved, too. Visual Basic was once again accessible to first-time developers. Since the 2005 release, Microsoft hasn t just been sitting on its laurels, as painful as that would be. It dug into its bag of tricks with both hands and came out with Visual Basic 2008, the latest VB offering. Formerly code-named Orcas, Visual Basic 2008 brings additional power and simplicity yes, both of those to the language. The biggest new feature, LINQ, makes data access easier by letting you tell the system what data you want instead of detailing how to obtain that data. The language also provides more direct access to new technologies such as Ajax and the Windows Presentation Foundation (WPF). But enough fawning. Let s start learning about the language.

Although ideal-gas heat capacities are exactly correct for real gases only at zero pressure, the departure of real gases from ideality is seldom significant at pressures below several bars, and here C and are usually good approximations to their heat capacities

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Gas mixtures of constant composition may be treated in exactly the same way as pure gases An ideal gas, by definition, is a gas whose molecules have no influence on one another This means that each gas in a mixture exists independent of the others; its properties are unaffected by the presence of different molecules Thus one calculates the ideal-gas heat capacity of a gas mixture as the mole-fraction-weighted sum of the heat capacities of the individual , species Consider 1 mol of gas mixture consisting of species A, B, and C , and let y ~ y , ~ and yc represent the mole fractions of these species The molar heat capacity of the mixture in the ideal-gas state is:

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