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Propagation by free ions ion pairs yields polymers molecular weight $104 ), while covalent propagation yields oligomers (molecular weight 600 700) (The low molecular weight of the latter indicates that extensive transfer to monomer occurs in competition with the slow propagation of the ester) The amount of the low-molecular-weight fraction relative to the high-molecular-weight fraction as observed in the SEC correlates with the fraction of the total reaction carried by the slow stage reaction as observed by rate measurements The high-molecular-weight fraction can be suppressed by the addition of a common ion salt such as tetra-n-butylammonium perchlorate, which pushes the equilibrium between ionic and covalent species toward the ester The extent of the slow stage reaction is dependent on both temperature and solvent It is observed only at 20 to 30 C and only in solvents that are no more polar than chlorinated hydrocarbons. vb.net ean 13 reader .NET EAN - 13 Barcode Reader for C#, VB . NET , ASP.NET Applications
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The disadvantage of this alternative is that an approximation is used in the problem. The second alternative is to use a dense grid with a large number of points (say more than 30 points) per free-space wavelength. We shall call such a gridding a single dense grid (SDG). We have shown in 4 that dense sampling of points is a requirement for energy conservation and an accurate calculation of emissivity. The disadvantage of this second alternative is that there is a large increase in CPU and required memory. The physics-based two-grid (PBTG) method to be discussed in this section is an improvement over these two alternatives in that it has the same accuracy as the single dense grid and yet has a CPU comparable with that of the single coarse grid. To demonstrate the accuracy of the PBTG method, we use it to calculate the emissivity of a random rough surface. In PBTG, two grids were used: a dense grid and a sparse grid. 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